Preheat oven to 350°F (176°C) and line a 9×9-inch baking dish with parchment paper.
Melt butter over low heat, then add chocolate chips, cocoa powder, and vanilla. Stir until smooth. Let cool slightly.
In a large bowl, beat eggs, egg yolk, brown sugar, and white sugar for 7–10 minutes until light and creamy.
Add sourdough discard and chocolate mixture, mixing gently until combined.
Fold in flour and salt until just incorporated. The batter will be thick.
Pour into the pan and smooth the top.
Bake for 35–40 minutes until a toothpick shows moist crumbs.
Cool completely before slicing your Sourdough Discard Brownies.